A popular activity in most college astronomy classes is to come up with a mnemonic to remember the sequence. One of the first, which has stuck since the early part of the century is:
Recall, we already had a method to estimate temperature of a star by studying its spectrum: Applying Wein's Law. The identification of atomic and molecular lines in the star is an even more powerful estimate for stellar temperature.
Not necessarily. A very careful analysis, taking into account the physical condition of the stars atmosphere, must be included, when determining the composition of a star. If Iron lines are seen to be very weak in the spectrum of a star, it could be the temperature is not right for the formation of that line, OR that the amount of iron in the star's atmosphere is low.